Connect with the -E option
psql -E .....

Then:

postgres=# \du
********* QUERY **********
SELECT r.rolname, r.rolsuper, r.rolinherit,
  r.rolcreaterole, r.rolcreatedb, r.rolcanlogin,
  r.rolconnlimit, r.rolvaliduntil,
  ARRAY(SELECT b.rolname
        FROM pg_catalog.pg_auth_members m
        JOIN pg_catalog.pg_roles b ON (m.roleid = b.oid)
        WHERE m.member = r.oid) as memberof
, r.rolreplication
, r.rolbypassrls
FROM pg_catalog.pg_roles r
WHERE r.rolname !~ '^pg_'
ORDER BY 1;
**************************

                                        List of roles
      Role name      |                         Attributes                         | Member of
---------------------+------------------------------------------------------------+-----------